NG ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEAS ABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERI IVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK ARE SK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL INT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS TIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAG E MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE C MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMEN HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ ECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES QUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ P ORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZA E CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXP NT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ COMBUSTIBLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATIO MIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TEC HPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQU STIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORA E MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE C MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMEN HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ ECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES QUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ P ORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZA E CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXP ENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION IMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TEC HPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQU STIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORA E MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE C MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMEN HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ ECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES QUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ P ORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZA E CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXP ENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION IMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TEC SHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ COMBUSTIBLE L MMABLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STO ECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STOR RDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASS LOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXP TION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQ IMIT ∙ RISK ASSESSMENT∙ Active storage of flammable liquids in safety storage cabinets – Explosion protection in practice Practical tips for your risk assessment for active storage redpaper Sample
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3 CONTENTS 1 2 3 4 5 6 7 1. Identifying hazardous materials and handling them correctly .........................................................................4 2. Safe storage of flammable liquids in work areas .................................................................................................5 3. Flammable liquids – classification, labelling and safety parameters ............................................................6 4. Three types of storage for flammable liquids.........................................................................................................8 5. Safety requirements for safety storage cabinets ..................................................................................................8 5.1 … according to EN 14470-1 ......................................................................................................................................8 5.2 Joint storage in safety storage cabinets ...................................................................................................................9 6. Assessment of explosion risk, occupational exposure limits and definition................................................10 6.1 Systematic approach to evaluating the explosion risk ........................................................................................10 6.2 Safety storage cabinets with technical ventilation ...............................................................................................12 6.3 Safety storage cabinets without technical ventilation .........................................................................................13 6.4 Zone classification in or on safety storage cabinets ............................................................................................14 6.5 Refilling tasks in the safety storage cabinet ............................................................................................................15 6.5.1 General information, measurement method and devices ...............................................................................15 6.5.2 Results of the measurement series and analysis ................................................................................................17 7. Summary ............................................................................................................................................................................26 Sample
4 The safe handling of hazardous materials is one of the most important tasks for the protection of the health of a company’s employees. The employer has many obligations. It must determine the potential hazard of the respective materials applied, specify the necessary work procedures and take suitable protective measures to safeguard the employees from health risks and protect the environment from damage caused by the use of these materials, following the STOP principle. Substitution of hazardous materials The rule of substitution generally applies: substituting hazardous materials with non-hazardous or less hazardous ones is the best way to avoid the risk of damage caused by hazardous materials. Many hazardous materials cannot be replaced or cannot yet be replaced or turned into less hazardous forms of use. Therefore, in most cases technical measures need to be taken to protect against the influences of hazardous materials. Explosive Compressed gases Flammable Category 1 Flammable Category 2 Flammable Category 3 Oxidising Category 1, 2, 3 Acute toxicity Category 1 Acute toxicity Category 2 Acute toxicity Category 3 Corrosive Category 1 Acute toxicity Category 4 Corrosive Category 2 Skin irritant CRM* Category 1A, 1B, 2 Respiratory sensitization Environmental pollutant Hazardous to the aquatic environment Explosive Non-existent Extremely flammable Highly flammable Flammable Oxidising Very toxic Very toxic resp. toxic Toxic resp. harmful Corrosive Harmful Irritant Non-existent Dangerous to the environment Non-existent no symbol GHS/CLP GefStoffV CMR*: C = carcinogenic, M = mutagenic, R = toxic to reproduction no symbol no symbol no symbol no symbol (German Ordinance on Hazardous Substances) Hazardous materials must be marked with hazard pictograms. In order to standardise the labelling of hazardous materials, previously different worldwide, the Globally Harmonised System (GHS) was introduced by the CLP regulation of the EU with a transitional period from 1st December 2010 for materials and from 1st June 2015 for mixtures. During this period, both the valid orange symbols and the new red and white GHS pictograms will be seen. The allocation of some of the hazards change, as different labelling systems from different countries have to be standardised. Instead of the previously used R codes, H codes are now used for the type and severity of the hazard, and P codes replace the S codes for the provision of safety information. Advantage: The new codes are more specific than their predecessors. 1. Identifying hazardous materials and handling them correctly Sample
5 Technical measures Technical measures are based on the following principles ` Avoidance of the escape of hazardous materials ` Extraction, preferably at their point of origin Organisational measures are: ` the determination of tasks and responsibilities, ` the selection and deployment of suitable employees, ` the implementation and monitoring of the regulations, ` the procurement of information regarding hazardous materials, ` the preparation of operating instructions with the following emphasis: Designation of the hazardous material • Danger for persons and environment • Protective measures and codes of conduct • Response in case of danger • First aid • Proper disposal ` Regular staff training ` Check the concentration of hazardous substances in the work area, ` Check technical facilities and personal protective equipment. Personal protective measures If technical and organisational measures are not sufficient to ensure protection against hazardous materials, personal protective equipment must also be provided by the company, and must be used by the employees in compliance with the operating instructions. The following personal protective equipment is recommended, depending on the parts of the body that are endangered: ` Protective clothing ` Protective gloves ` Protective footwear ` Eye, face and head protection ` Respiratory protection 2. Safe storage of flammable liquids in work areas Safe storage of flammable liquids in bottles, canisters or barrels in work areas plays an important role in the risk assessment – in particular with respect to fire and explosion protection. The primary safety objective is to minimise the fire load in the work areas and prevent the stored substances from causing an additional hazard. State of the art safety storage cabinets with a defined fire resis- tance have proven an effective solution for many years. In addition, it is necessary to determine whether and, if so, to what extent additional explosion protection measures are needed. Sample
OSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLIN S ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMA ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTI PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RIS AS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOI VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUST ABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE AMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS M T ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION H ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ W LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TE SHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQ USTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STO TIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSME HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ FLAMMABLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LI AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASH VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUS ABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE AMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS M T ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION H ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ W LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TE SHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQ USTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STO TIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSME AZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LI AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASH VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUS ABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE AMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS M T ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION H ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ W LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TE SHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQ USTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STO TIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSMENT ∙ SAFETY STORAGE MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LIMIT ∙ RISK ASSESSME AZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLASHPOINT ∙ EXPLOSION LI K AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ COMBUSTIBLE LIQUIDS ∙ FLAS ICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTECTIVE MEASURES ∙ FLAM DS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZARDOUS MATERIALS ∙ PROTE AGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPLOSION HAZARD ∙ HAZAR E CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILATION ∙ WORK AREAS ∙ EXPL SMENT ∙ SAFETY STORAGE CABINET ∙ ACTIVE STORAGE ∙ FLAMMABLE LIQUIDS ∙ LABELLING ∙ TECHNICAL VENTILAT POINT ∙ EXP For all other countries please contact asecos Headquarters in Germany. © asecos GmbH 04/2024 asecos GmbH Sicherheit und Umweltschutz Weiherfeldsiedlung 16–18 DE-63584 Gründau +49 6051 92200 +49 6051 922010 info@asecos.com asecos Ltd. 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Have you considered the potential impacts of a fire of flammable liquids? Our video illustrates the fire resistance of 3 different types of safety storage cabinets typically used to store flammable liquids. VIEW NOW: www.youtube.com/asecoschannel Sample
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